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Beilstein J. Org. Chem. 2011, 7, 1520–1525, doi:10.3762/bjoc.7.178
Graphical Abstract
Scheme 1: Proposed metal catalyzed annulation for the synthesis of triaryldiacenaphtho[1,2-j:1',2'-l]fluorant...
Figure 1: Cationic gold complexes 5 and 6.
Scheme 2: Pd(OAc)2-catalyzed isomerization of 7a to form (E)-9-(3-phenylallylidene)-9H-fluorene (9).
Scheme 3: Gold(I)-catalyzed hydroarylation of 7k to give 1,10b-dihydrofluoranthene 9.
Scheme 4: Gold(I)-catalyzed triple hydroarylation of 1a,b to give 2a,b.